钛合金无缝管热连轧温度场模拟

采用有限元法分析了钛合金无缝管多机架连轧下的温度状态。模拟结果表明：随轧制道次的增加,辊底下的外表面温度以逐渐减缓的速率降低,中心温度整体上以逐渐减缓的速率上升,而辊缝下外表面温度持续升高。中心温度的周向不均匀性在奇数道次时减小,在偶数道次时增大,而外表面温度分布的不均匀性与此相反。前一机架压下量与后机架辊缝处温升呈负相关,降低前一机架压下量可显著提升后机架周向温度不均匀性。温度测量和晶粒形貌分析的结果表明,模拟结果与实验结果吻合度较高。     

熔炼时间对稀土单晶合金坩埚界面反应的影响

为了实现稀土单晶高温合金中稀土含量的稳定控制,明确稀土元素在熔炼过程中参与的坩埚界面反应机理,研究了熔炼时间对含Y高温合金CMSX-4与Al2O3陶瓷坩埚在真空感应熔炼过程中的界面反应和稀土Y收得率的影响。实验结果表明：随着熔炼时间的延长界面反应加剧,熔炼过程中Y首先与Al2O3陶瓷基体发生反应生成Y2O3,生成的Y2O3会继续与Al2O3发生反应生成Y、Al原子比不同的铝酸钇反应层,最终坩埚表面形成的界面反应产物由外层的YAlO3、内层的Y3Al5O12(Y3Al2(AlO4)3) 以及附着的高温合金组成。熔炼10~30min时合金中稀土Y收得量为41.023、4.566和5.368ppm。     

从铜冶炼烟气酸洗液中分离富集铼

铜冶炼烟气酸洗液经D296阴离子交换树脂吸附后,再依次采用氨水解吸Sb,NaOH和酒石酸混合溶液解吸Bi,NH₄SCN溶液解吸Re,实现Re/Sb/Bi的分步解吸并获得铼富集液。结果表明：酸洗液电位对Re、Sb、Bi吸附率没有明显影响,适宜的酸洗液H₂SO₄浓度为43.81 g·L^-1,Re、Sb、Bi吸附率分别为100%、6.55%和89.05%;D296树脂吸附Re的穿透容量和饱和容量分别为1.308和1.773 g·L^-1,且树脂利用率为73.77%;先采用12.5%氨水解吸Sb,16%NaOH+140 g·L^-1酒石酸混合溶液解吸Bi,通过添加酒石酸可有效抑制Bi水解,再采用10%NH₄SCN溶液解吸Re,得到铼富集液,其Cu、As、Sb、Bi浓度均降至1 mg·L^-1以下,且使酸洗液中Re富集了4倍。     

WC涂层纳米划痕过程中摩擦学性能及演化特征的分子动力学研究

为研究纳米划擦过程中WC涂层纳米级摩擦演化特征,利用大型原子/分子大规模并行模拟器建立了不同条件（载荷、划痕深度、划痕速度）下的分子动力学模拟模型。结果表明：摩擦力和摩擦系数随着划痕深度的增加而增大;当压头划擦试样时,沿划痕方向在压头前方及凹槽两侧的原子被挤压、剪切、堆积。瞬时摩擦曲线在初始阶段和稳定阶段表现出明显的摩擦学特征,摩擦过程中压头下方区域晶体出现错位、滑移、间隙或空位。随着划痕速度的增加,体系应变能超过原子间相互约束,原子突破约束,在划痕沟槽两侧堆积,堆积的表面形貌和外缘变得粗糙,亚表面晶体结构产生缺陷。本研究有助于在纳米尺度了解WC涂层摩擦过程的微观磨损机理。     

Simple N‐Heterocyclic Carbenes as Ligands in Ullmann‐Type Ether and Thioether Formations

A simple N‐heterocyclic carbene (NHC) derived from 1‐methyl‐3‐ethylimidazolium tetrafluoroborate was found to be an efficient ligand for a range of copper‐catalyzed cross‐coupling reactions, leading to the formation of aromatic ethers and thioethers.

     

Zentrische Druckversuche an schlanken UHPC‐Stützen

Axial compression tests on slender columns – unreinforced slender columns: a taboo? – Debate on potential and risk Within the project of the Priority Programme (SPP) 1542 ”Concrete light“, which is funded by the German Research Foundation (DFG), unreinforced UHPC columns with square and rectangular cross‐section were tested under axial compression in the subproject ”Cross sectional adaption for rod‐shaped elements in compression“. The results were compared with test series of other researchers. The focus of the study was on the buckling behavior of columns with different conditions of end support. A hinged and a fixed support have been applied for these experiments. In addition to an analysis of the failure process, the results were compared with the Euler buckling load and the normal stress in consideration of second‐order effects. Concluding, advantages and disadvantages of both approaches are presented, compared, and discussed.     

Verbundverhalten von Vollgewindeschrauben in Brettschichtholzbauteilen

Bond behaviour of self‐tapping screws being used as reinforcement in glue‐laminated timber elements – Part 2: Analytical and numerical investigations as well bond model derivation for the calculation of anchorage length In favor of the investigation of bond behaviour, force transfer and anchorage length of self‐tapping screws, several tests have been realized at the Chair of Structures and Structural Design in cooperation with the Institute for Building Material Research of the RWTH Aachen University. The experimental investigations comprise more than 160 pull‐out tests of screws with long embedment length and over 84 load distributions tests. Additionally, several tests displaying the effect of longitudinal cracks in the surrounding wood as well as the effect of the screw tip have been conducted. Through various analyses of the bond behaviour, the experimental investigations form the basis for the calibration and evaluation of the numerical models and allow a prediction of the force transfer of the screws in glue‐laminated elements. Design rules that enable the application of the self‐tapping screws as reinforcement in timber elements have been derived from the knowledge obtained in the experimental and numerical investigations. This paper, which results from a research project funded by the German Research Foundation [1], presents the results of investigations on the bond behavior of self‐tapping screws in glue‐laminated timber elements. Part 1 elaborates on the experimental investigations [2] whereas part 2 illustrates the numerical analyses and presents a bond model, which enables the design of the anchorage length and the safe application of the screws as reinforcement in timber elements.